Highly Diastereoselective Reformatsky-Type Reaction Promoted by Tin Iodide Ate Complex

An ate type of tin complex, Li+[n-Bu2SnI3]-/HMPA, works as a novel type of reagent to accomplish the highly diastereoselective Reformatsky-type reaction by the halogen−metal exchange method.

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Bibliographische Detailangaben
Veröffentlicht in:	Organic letters 2002-01, Vol.4 (2), p.301-303
Hauptverfasser:	Shibata, Ikuya, Suwa, Toshihiro, Sakakibara, Hideaki, Baba, Akio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	An ate type of tin complex, Li+[n-Bu2SnI3]-/HMPA, works as a novel type of reagent to accomplish the highly diastereoselective Reformatsky-type reaction by the halogen−metal exchange method.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol0171214