Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior
A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interes...
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Veröffentlicht in: | Journal of organic chemistry 2003-11, Vol.68 (24), p.9473-9476 |
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container_issue | 24 |
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container_title | Journal of organic chemistry |
container_volume | 68 |
creator | Cappelli, Andrea Pericot Mohr, Gal.la Anzini, Maurizio Vomero, Salvatore Donati, Alessandro Casolaro, Mario Mendichi, Raniero Giorgi, Gianluca Makovec, Francesco |
description | A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported. |
doi_str_mv | 10.1021/jo035104h |
format | Article |
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This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. 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Org. Chem</addtitle><description>A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.</description><subject>Alicyclic compounds</subject><subject>Alicyclic compounds, terpenoids, prostaglandins, steroids</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><issn>0022-3263</issn><issn>1520-6904</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNpt0EuP0zAUBWALgZjOwII_gLIBaRYBv1MvmYqnKhipRbCzbtwb4iGJBzvp0Pn1GLW0G7zxwp-Ojg8hzxh9xShnr28CFYpR2T4gM6Y4LbWh8iGZUcp5KbgWZ-Q8pRuaj1LqMTljUnPDKjkjYbUbxhaTTwUMm2LRQgQ3YvT3MPowFKEpoPiMd8UVDvehmbotDlhch27XYyxWbbjzw49M1i3GPkTcYky-7o7kX84VtrD1IT4hjxroEj493Bfk67u368WHcvnl_cfFm2UJUqqxRI2MNbkuxwrkXNZCzM2GsroGWmnKG82McA6cqbUDU81FpdGISiGvEUUjLsjLfe5tDL8mTKPtfXLYdTBgmJKtmDCSUZHh5R66GFKK2Njb6HuIO8uo_buuPa6b7fND6FT3uDnJw5wZvDgASA66JsLgfDo5JZiilGVX7p1PI_4-vkP8aXWVf2HX1ys7N2r5aaG_2e-nXHAp95nikLf7T8E_bnKedQ</recordid><startdate>20031128</startdate><enddate>20031128</enddate><creator>Cappelli, Andrea</creator><creator>Pericot Mohr, Gal.la</creator><creator>Anzini, Maurizio</creator><creator>Vomero, Salvatore</creator><creator>Donati, Alessandro</creator><creator>Casolaro, Mario</creator><creator>Mendichi, Raniero</creator><creator>Giorgi, Gianluca</creator><creator>Makovec, Francesco</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20031128</creationdate><title>Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior</title><author>Cappelli, Andrea ; Pericot Mohr, Gal.la ; Anzini, Maurizio ; Vomero, Salvatore ; Donati, Alessandro ; Casolaro, Mario ; Mendichi, Raniero ; Giorgi, Gianluca ; Makovec, Francesco</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a445t-e6e11f0052e7a484b3389d01bba07602f6193ccac9b6ca978376e9375e2bee3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Alicyclic compounds</topic><topic>Alicyclic compounds, terpenoids, prostaglandins, steroids</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cappelli, Andrea</creatorcontrib><creatorcontrib>Pericot Mohr, Gal.la</creatorcontrib><creatorcontrib>Anzini, Maurizio</creatorcontrib><creatorcontrib>Vomero, Salvatore</creatorcontrib><creatorcontrib>Donati, Alessandro</creatorcontrib><creatorcontrib>Casolaro, Mario</creatorcontrib><creatorcontrib>Mendichi, Raniero</creatorcontrib><creatorcontrib>Giorgi, Gianluca</creatorcontrib><creatorcontrib>Makovec, Francesco</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cappelli, Andrea</au><au>Pericot Mohr, Gal.la</au><au>Anzini, Maurizio</au><au>Vomero, Salvatore</au><au>Donati, Alessandro</au><au>Casolaro, Mario</au><au>Mendichi, Raniero</au><au>Giorgi, Gianluca</au><au>Makovec, Francesco</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior</atitle><jtitle>Journal of organic chemistry</jtitle><addtitle>J. Org. Chem</addtitle><date>2003-11-28</date><risdate>2003</risdate><volume>68</volume><issue>24</issue><spage>9473</spage><epage>9476</epage><pages>9473-9476</pages><issn>0022-3263</issn><eissn>1520-6904</eissn><coden>JOCEAH</coden><abstract>A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>14629174</pmid><doi>10.1021/jo035104h</doi><tpages>4</tpages></addata></record> |
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source | ACS Publications |
subjects | Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties |
title | Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior |
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