Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior

A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interes...

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Veröffentlicht in:	Journal of organic chemistry 2003-11, Vol.68 (24), p.9473-9476
Hauptverfasser:	Cappelli, Andrea, Pericot Mohr, Gal.la, Anzini, Maurizio, Vomero, Salvatore, Donati, Alessandro, Casolaro, Mario, Mendichi, Raniero, Giorgi, Gianluca, Makovec, Francesco
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo035104h