Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars
A variety of cyclic and acyclic allylic alcohols undergo efficient chemo-, regio- and/or stereoselective epoxidations in neutral aqueous solutions of amphiphilic carbohydrates (sucrose, L-arabinose, methyl or ethyl beta-D-fructopyranoside) by using dilute hydrogen peroxide in the presence of molybdi...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2001-12 (23), p.2460-2461 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A variety of cyclic and acyclic allylic alcohols undergo efficient chemo-, regio- and/or stereoselective epoxidations in neutral aqueous solutions of amphiphilic carbohydrates (sucrose, L-arabinose, methyl or ethyl beta-D-fructopyranoside) by using dilute hydrogen peroxide in the presence of molybdic or tungstic salts. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b108352j |