Rapid and Versatile Synthesis of Functionalized Polyhydroxylated Fragments
The condensation between a functionalized allylstannane and α-alkoxyaldehydes allows rapid access to complex and selectively protected trihydroxylated synthons. The stereocontrol of this process is strongly dependent upon the nature and the amount of the Lewis acid employed.
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Veröffentlicht in: | Organic letters 2002-01, Vol.4 (1), p.47-50 |
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creator | Leroy, Bernard Markó, István E |
description | The condensation between a functionalized allylstannane and α-alkoxyaldehydes allows rapid access to complex and selectively protected trihydroxylated synthons. The stereocontrol of this process is strongly dependent upon the nature and the amount of the Lewis acid employed. |
doi_str_mv | 10.1021/ol016863u |
format | Article |
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subjects | Aldehydes - chemistry Allyl Compounds - chemistry Hydroxylation Indicators and Reagents Molecular Conformation Organotin Compounds - chemistry Stereoisomerism |
title | Rapid and Versatile Synthesis of Functionalized Polyhydroxylated Fragments |
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