Rapid and Versatile Synthesis of Functionalized Polyhydroxylated Fragments

The condensation between a functionalized allylstannane and α-alkoxyaldehydes allows rapid access to complex and selectively protected trihydroxylated synthons. The stereocontrol of this process is strongly dependent upon the nature and the amount of the Lewis acid employed.

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Veröffentlicht in:Organic letters 2002-01, Vol.4 (1), p.47-50
Hauptverfasser: Leroy, Bernard, Markó, István E
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creator Leroy, Bernard
Markó, István E
description The condensation between a functionalized allylstannane and α-alkoxyaldehydes allows rapid access to complex and selectively protected trihydroxylated synthons. The stereocontrol of this process is strongly dependent upon the nature and the amount of the Lewis acid employed.
doi_str_mv 10.1021/ol016863u
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source MEDLINE; ACS Publications
subjects Aldehydes - chemistry
Allyl Compounds - chemistry
Hydroxylation
Indicators and Reagents
Molecular Conformation
Organotin Compounds - chemistry
Stereoisomerism
title Rapid and Versatile Synthesis of Functionalized Polyhydroxylated Fragments
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