Minimal model for Beta relaxation in viscous liquids

Contrasts between beta relaxation in equilibrium viscous liquids and glasses are rationalized in terms of a double-well potential model with structure-dependent asymmetry, assuming structure is described by a single order parameter. The model is tested for tripropylene glycol where it accounts for t...

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Veröffentlicht in:Physical review letters 2003-10, Vol.91 (15), p.155703-155703
Hauptverfasser: Dyre, Jeppe C, Olsen, Niels Boye
Format: Artikel
Sprache:eng
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Zusammenfassung:Contrasts between beta relaxation in equilibrium viscous liquids and glasses are rationalized in terms of a double-well potential model with structure-dependent asymmetry, assuming structure is described by a single order parameter. The model is tested for tripropylene glycol where it accounts for the hysteresis of the dielectric beta loss peak frequency and magnitude during cooling and reheating through the glass transition.
ISSN:0031-9007
DOI:10.1103/PhysRevLett.91.155703