One-way EZ-isomerization of bis(n-butylammonium) (Z,Z)-muconate under photoirradiation in the crystalline state

One-way EZ-isomerization of bis(n-butylammonium) (Z,Z)-muconate under photoirradiation in the crystalline state

One-way EZ-isomerization of bis(n-butylammonium) (Z,Z)-muconate [(Z,Z)-hexa-2,4-diene-1,6-dioate] to the corresponding (E,E)-isomer quantitatively proceeded in the crystalline state under photoirradiation with a high-pressure mercury lamp, being a new type of crystal-to-crystal reaction.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2001-10 (19), p.2004-2005
Hauptverfasser: Odani, T, Matsumoto, A, Sada, K, Miyata, M
Format: Artikel
Sprache:eng
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Zusammenfassung:One-way EZ-isomerization of bis(n-butylammonium) (Z,Z)-muconate [(Z,Z)-hexa-2,4-diene-1,6-dioate] to the corresponding (E,E)-isomer quantitatively proceeded in the crystalline state under photoirradiation with a high-pressure mercury lamp, being a new type of crystal-to-crystal reaction.
ISSN:1359-7345
1364-548X
DOI:10.1039/b106155k