Solid state evidence for pi-complexation of sodium cation by carbon-carbon double bonds

Solid state evidence for pi-complexation of sodium cation by carbon-carbon double bonds

Solid state evidence shows that neutral double bonds, attached to flexible sidearms of a lariat ether, serve as intramolecular pi-donors for a ring-bound Na+ cation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2001-09 (18), p.1858-1859
Hauptverfasser: Hu, J, Barbour, L J, Gokel, G W
Format: Artikel
Sprache:eng
Schlagworte:
Carbon - chemistry
Cations - chemistry
Ethers, Cyclic - chemistry
Models, Molecular
Molecular Conformation
Sodium - chemistry
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Beschreibung
Zusammenfassung:Solid state evidence shows that neutral double bonds, attached to flexible sidearms of a lariat ether, serve as intramolecular pi-donors for a ring-bound Na+ cation.
ISSN:1359-7345
1364-548X
DOI:10.1039/b106589k