Novel synthesis of cyclobutanone derivatives via dimetalation of iminium ions with the TiCl4-trialkylamine reagent system

Novel synthesis of cyclobutanone derivatives via dimetalation of iminium ions with the TiCl4-trialkylamine reagent system

Iminium salts are generated in situ, react with TiCl4-trialkylamines, and diaryl ketones to produce 3,3-diaryl-cyclobutanones in moderate to good yields.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2001-09 (18), p.1728-1729
Hauptverfasser: Periasamy, M, Jayakumar, K N, Bharathi, P
Format: Artikel
Sprache:eng
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Zusammenfassung:Iminium salts are generated in situ, react with TiCl4-trialkylamines, and diaryl ketones to produce 3,3-diaryl-cyclobutanones in moderate to good yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/b103112k