Dioxygen activation by a neutral beta-diketiminato copper(I) ethylene complex
The synthesis and structure of two thermally stable neutral beta-diketiminato copper(I) olefin complexes are presented along with the structure of a Cu(II)2(mu-OH)2 dimer that results from the reaction of the Cu(I) ethylene complex with O2 via the proposed intermediacy of a Cu(III)2(mu-O)2 species.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2001-10 (19), p.1998-1999 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis and structure of two thermally stable neutral beta-diketiminato copper(I) olefin complexes are presented along with the structure of a Cu(II)2(mu-OH)2 dimer that results from the reaction of the Cu(I) ethylene complex with O2 via the proposed intermediacy of a Cu(III)2(mu-O)2 species. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b105244f |