Triprotic 2,4,6-tris(organoamino)-1,3,5-triazenes as precursors to multi-site triazenate ligands

Triprotic 2,4,6-tris(organoamino)-1,3,5-triazenes as precursors to multi-site triazenate ligands

2,4,6-Tris(2-fluoroanilino)-1,3,5-triazene successively undergoes one-, two- and three-fold deprotonation in the presence of BunLi; the dilithiated triazenate exists as the dimeric complex (thf)6Li4[(RN)2(RNH)C3N3]2 in the solid state (R = 2-F-C6H4) featuring bidentate Nendo-C-Nexo chelation sites.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2001-10 (20), p.2104-2105
Hauptverfasser: Rivals, F, Steiner, A
Format: Artikel
Sprache:eng
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Zusammenfassung:2,4,6-Tris(2-fluoroanilino)-1,3,5-triazene successively undergoes one-, two- and three-fold deprotonation in the presence of BunLi; the dilithiated triazenate exists as the dimeric complex (thf)6Li4[(RN)2(RNH)C3N3]2 in the solid state (R = 2-F-C6H4) featuring bidentate Nendo-C-Nexo chelation sites.
ISSN:1359-7345
DOI:10.1039/b105435j