Photosensitized (Electron-Transfer) Deconjugation of 1-Arylcyclohexenes

A series of 1-arylcyclohexenes have been deconjugated to the corresponding 3-arylcyclohexenes via a photosensitized electron-transfer reaction. The introduction of substituents on the aryl group has provided insight into the underlying mechanism and has defined the scope and limitations of the react...

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Veröffentlicht in:Organic letters 2001-01, Vol.3 (1), p.45-48
Hauptverfasser: Mangion, Dino, Kendall, Jamie, Arnold, Donald R
Format: Artikel
Sprache:eng
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Zusammenfassung:A series of 1-arylcyclohexenes have been deconjugated to the corresponding 3-arylcyclohexenes via a photosensitized electron-transfer reaction. The introduction of substituents on the aryl group has provided insight into the underlying mechanism and has defined the scope and limitations of the reaction.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006755s