Organolanthanide-Catalyzed Cyclization/Boration of 1,5- and 1,6-Dienes

Organolanthanide-Catalyzed Cyclization/Boration of 1,5- and 1,6-Dienes

1,5- and 1,6-Dienes undergo a cyclization/boration reaction in the presence of a catalytic amount of Cp*2Sm·THF. The resulting organoboranes can be oxidized to the corresponding primary cyclic alcohols using standard conditions.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2001-02, Vol.3 (3), p.361-363
Hauptverfasser: Molander, Gary A, Pfeiffer, Dirk
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols - chemical synthesis
Alkenes - chemistry
Boranes - chemistry
Hydrocarbons, Cyclic - chemical synthesis
Organometallic Compounds - chemistry
Samarium - chemistry
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Beschreibung
Zusammenfassung:1,5- and 1,6-Dienes undergo a cyclization/boration reaction in the presence of a catalytic amount of Cp*2Sm·THF. The resulting organoboranes can be oxidized to the corresponding primary cyclic alcohols using standard conditions.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006841s