Catalytic Asymmetric Vinylation of Ketone Enolates

Catalytic Asymmetric Vinylation of Ketone Enolates

A protocol for the catalytic asymmetric vinylation of ketone enolates has been developed. Key to the success of this process was the development of new electron-rich chiral monodentate ligands.

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Veröffentlicht in:Organic letters 2001-06, Vol.3 (12), p.1897-1900
Hauptverfasser: Chieffi, André, Kamikawa, Ken, Åhman, Jens, Fox, Joseph M, Buchwald, Stephen L
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Ketones - chemistry
Vinyl Compounds - chemistry
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Zusammenfassung:A protocol for the catalytic asymmetric vinylation of ketone enolates has been developed. Key to the success of this process was the development of new electron-rich chiral monodentate ligands.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0159470