Synthesis of Configurationally Defined Sexi- and Octinaphthalene Derivatives

Synthesis of Configurationally Defined Sexi- and Octinaphthalene Derivatives

Configurationally defined optically active octinaphthalenes were synthesized using the oxidative coupling of optically active quaternaphthalenes with a 2-hydroxynaphthol moiety as a key reaction. The absolute configuration was determined by comparison with products of [6 + 2] coupling.

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Veröffentlicht in:Organic letters 2001-01, Vol.3 (2), p.169-171
Hauptverfasser: Fuji, Kaoru, Furuta, Takumi, Tanaka, Kiyoshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Configurationally defined optically active octinaphthalenes were synthesized using the oxidative coupling of optically active quaternaphthalenes with a 2-hydroxynaphthol moiety as a key reaction. The absolute configuration was determined by comparison with products of [6 + 2] coupling.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006843c