Structural, CV and IR Spectroscopic Evidences for Preorientation in PET-Active Phthalimido Carboxylic Acids

Structural, CV and IR Spectroscopic Evidences for Preorientation in PET-Active Phthalimido Carboxylic Acids

Hydrogen bond and potassium cation mediated preorientation were detected for phthalimido acetic acid and the corresponding acetate. Evidence for these phenomena came from X-ray structure analysis as well as cyclic voltammetric and IR spectroscopic measurements. These interactions rationalize the pho...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2001-05, Vol.3 (11), p.1593-1596
Hauptverfasser: Oelgemöller, Michael, Griesbeck, Axel G, Lex, Johann, Haeuseler, Andreas, Schmittel, Michael, Niki, Makiko, Hesek, Dusan, Inoue, Yoshihisa
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Hydrogen bond and potassium cation mediated preorientation were detected for phthalimido acetic acid and the corresponding acetate. Evidence for these phenomena came from X-ray structure analysis as well as cyclic voltammetric and IR spectroscopic measurements. These interactions rationalize the photoinduced electron transfer (PET) reactivity of the substrates in photodecarboxylation reactions.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0155900