Chemoselective Cross-Metathesis Reaction. Application to the Synthesis of the C1−C14 Fragment of Amphidinol 3

Chemoselective Cross-Metathesis Reaction. Application to the Synthesis of the C1−C14 Fragment of Amphidinol 3

An efficient synthesis of the C1−C14 fragment of amphidinol 3 is described. The synthesis is based on chemoselective cross-metathesis reactions and enantioselective allyltitanations.

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Veröffentlicht in:Organic letters 2001-05, Vol.3 (10), p.1451-1454
Hauptverfasser: BouzBouz, Samir, Cossy, Janine
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemical synthesis
Animals
Antifungal Agents - chemical synthesis
Dinoflagellida - chemistry
Molecular Structure
Pyrans - chemical synthesis
Stereoisomerism
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Zusammenfassung:An efficient synthesis of the C1−C14 fragment of amphidinol 3 is described. The synthesis is based on chemoselective cross-metathesis reactions and enantioselective allyltitanations.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0157095