On the Absolute Configuration of Matricin

Abstract The assignment of the absolute configuration of matricin rests on indirect evidence. On the basis of synthetic, NMR and CD studies with its decomposition product, chamazulene carboxylic acid, we were able to firmly establish the accepted 3S,3aR,4S,9R,9aS,9bS configuration of matricin.

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Bibliographische Detailangaben
Veröffentlicht in:	Planta medica 2001-04, Vol.67 (3), p.292-294
Hauptverfasser:	Goeters, Susanne, Imming, Peter, Pawlitzki, Gregor, Hempel, Bernd
Format:	Artikel
Sprache:	eng
Schlagworte:	Anti-Inflammatory Agents, Non-Steroidal - chemistry Anti-Inflammatory Agents, Non-Steroidal - isolation & purification Biological and medical sciences Chamomile - chemistry General pharmacology Lactones Letter Magnetic Resonance Imaging Medical sciences Molecular Conformation Molecular Structure Pharmacognosy. Homeopathy. Health food Pharmacology. Drug treatments Plant Extracts - chemistry Plant Extracts - isolation & purification Plants, Medicinal Sesquiterpenes - chemistry Sesquiterpenes - isolation & purification
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Beschreibung
Zusammenfassung:	Abstract The assignment of the absolute configuration of matricin rests on indirect evidence. On the basis of synthetic, NMR and CD studies with its decomposition product, chamazulene carboxylic acid, we were able to firmly establish the accepted 3S,3aR,4S,9R,9aS,9bS configuration of matricin.
ISSN:	0032-0943 1439-0221
DOI:	10.1055/s-2001-11998