State-to-state chemical reaction dynamics in polyatomic systems: case studies

This review illustrates the experimental study of chemical reaction dynamics using methods that select the quantum states and energy of the reactants and determine the quantum states and energy of the products. The focus is reaction dynamics in systems in which at least one of the reactants or produ...

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Veröffentlicht in:Annual review of physical chemistry 2001, Vol.52, p.15-39
1. Verfasser: Valentini, J J
Format: Artikel
Sprache:eng
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Zusammenfassung:This review illustrates the experimental study of chemical reaction dynamics using methods that select the quantum states and energy of the reactants and determine the quantum states and energy of the products. The focus is reaction dynamics in systems in which at least one of the reactants or products is a polyatomic molecule. The approach taken is to select four prototype reaction systems as case studies to demonstrate the detail of information and insight that can come from such experiments. Thus, the review is selective and neither claims nor attempts to be comprehensive. Reference to and discussion of theoretical reaction dynamics are included where computational results directly connect with the experiments.
ISSN:0066-426X
1545-1593
DOI:10.1146/annurev.physchem.52.1.15