Anion complexation via C-H...X interactions using a palladacyclic receptor

Anion complexation via C-H...X interactions using a palladacyclic receptor

A novel organometallic receptor binds anions in solution and in the solid state, with complexes stabilised through a series of C-HX interactions, as evidenced by 1H NMR spectroscopy, X-ray crystallography and computational models.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-06 (21), p.2429-2431
Hauptverfasser: Bedford, Robin B, Betham, Michael, Butts, Craig P, Coles, Simon J, Hursthouse, Michael B, Noelle Scully, P, Tucker, James H R, Wilkie, John, Willener, Yasmine
Format: Artikel
Sprache:eng
Schlagworte:
Anions - chemistry
Computer Simulation
Crystallography, X-Ray
Cyclization
Hydrogen Bonding
Magnetic Resonance Spectroscopy - methods
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Palladium - chemistry
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Beschreibung
Zusammenfassung:A novel organometallic receptor binds anions in solution and in the solid state, with complexes stabilised through a series of C-HX interactions, as evidenced by 1H NMR spectroscopy, X-ray crystallography and computational models.
ISSN:1359-7345
DOI:10.1039/b801823e