Monodentate, N-Heterocyclic Carbene-Type Coordination of 2,2'-Bipyridine and 1,10-Phenanthroline to Iridium

Monodentate, N-Heterocyclic Carbene-Type Coordination of 2,2'-Bipyridine and 1,10-Phenanthroline to Iridium

Unusual Carbenes: 2,2′‐Bipyridine and 1,10‐phenanthroline are capable of coordinating to iridium as monodentate N‐heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5‐dimethylpyraz...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-05, Vol.47 (23), p.4380-4383
Hauptverfasser: Conejero, Salvador, Lara, Patricia, Paneque, Margarita, Petronilho, Ana, Poveda, Manuel L, Serrano, Oracio, Vattier, Florencia, Álvarez, Eleuterio, Maya, Celia, Salazar, Verónica, Carmona, Ernesto
Format: Artikel
Sprache:eng
Schlagworte:
iridium
N ligands
N-heterocyclic carbenes
nitrogen heterocycles
polypyridines
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Zusammenfassung:Unusual Carbenes: 2,2′‐Bipyridine and 1,10‐phenanthroline are capable of coordinating to iridium as monodentate N‐heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5‐dimethylpyrazolyl)borate]iridium.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200800705