The Aza-type-B photochemical rearrangement : The role of a second carbonyl in heterocyclic photochemistry. Mechanistic and exploratory organic photochemistry

In contrast to the photochemistry of monocyclic aza-cyclohexenones, their counterparts with a second carbonyl group undergo photochemical rearrangements which parallel those of the 4,4-disubstituted cyclohexenones.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2007-08, Vol.72 (16), p.6091-6096
Hauptverfasser:	ZIMMERMAN, Howard E, MITKIN, Oleg D
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology General and physical chemistry Kinetics and mechanisms Organic chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Preparations and properties Reactivity and mechanisms
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Beschreibung
Zusammenfassung:	In contrast to the photochemistry of monocyclic aza-cyclohexenones, their counterparts with a second carbonyl group undergo photochemical rearrangements which parallel those of the 4,4-disubstituted cyclohexenones.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo0706372