A photochemical route to discrete, ternary metal chalcogenide clusters

A photochemical route to discrete, ternary metal chalcogenide clusters

Ternary clusters Cu(9)In(10)S(9)(SEt)(21)(PPh(3))(3) and Cu(11)In(6)S(7)(S(t)Bu)(15) were isolated from the UV-photolysis products of precursors (PPh(3))(2)CuIn(SEt)(4) and (PPh(3))(2)CuIn(S(t)Bu)(4), respectively, and structurally characterized.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (30), p.3177-3179
Hauptverfasser: Williams, Mark, Okasha, Rawda M, Nairn, Justin, Twamley, Brendan, Afifi, Tarek H, Shapiro, Pamela J
Format: Artikel
Sprache:eng
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Zusammenfassung:Ternary clusters Cu(9)In(10)S(9)(SEt)(21)(PPh(3))(3) and Cu(11)In(6)S(7)(S(t)Bu)(15) were isolated from the UV-photolysis products of precursors (PPh(3))(2)CuIn(SEt)(4) and (PPh(3))(2)CuIn(S(t)Bu)(4), respectively, and structurally characterized.
ISSN:1359-7345
1364-548X
DOI:10.1039/b702541f