Diarylprolinol Silyl Ether as Catalyst of an exo-Selective, Enantioselective Diels−Alder Reaction

Diarylprolinol Silyl Ether as Catalyst of an exo-Selective, Enantioselective Diels−Alder Reaction

In combined use with CF3CO2H, 2-[bis(3,5-bis-trifluoromethylphenyl) triethylsiloxymethyl]pyrrolidine was found to be an effective organocatalyst of an exo-selective, enantioselective Diels−Alder reaction of α,β-unsaturated aldehydes.

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Veröffentlicht in:Organic letters 2007-07, Vol.9 (15), p.2859-2862
Hauptverfasser: Gotoh, Hiroaki, Hayashi, Yujiro
Format: Artikel
Sprache:eng
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Zusammenfassung:In combined use with CF3CO2H, 2-[bis(3,5-bis-trifluoromethylphenyl) triethylsiloxymethyl]pyrrolidine was found to be an effective organocatalyst of an exo-selective, enantioselective Diels−Alder reaction of α,β-unsaturated aldehydes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol071009+