Molecular Architecture towards Helical Double-Stranded Polymers

Close to original: A DNA‐like double‐stranded polymer is synthesized by ring‐opening metathesis polymerization of a bisnorbornene derivative containing a rigid ferrocene spacer. The polymer forms helices (see picture), supercoils, and ladders, which are observable by scanning tunneling microscopy....

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2006-01, Vol.45 (5), p.726-730
Hauptverfasser:	Yang, Hui-Chun, Lin, Shu-Yi, Yang, Hsiao-Ching, Lin, Cheng-Lan, Tsai, Lun, Huang, Shou-Ling, Chen, I. Wen-Peter, Chen, Chun-hsien, Jin, Bih-Yaw, Luh, Tien-Yau
Format:	Artikel
Sprache:	eng
Schlagworte:	Ferrous Compounds - chemistry helical structures Magnetic Resonance Spectroscopy - methods Metallocenes metathesis Models, Molecular molecular modeling Molecular Structure Norbornanes - chemical synthesis Norbornanes - chemistry Polymers - chemical synthesis Polymers - chemistry ring-opening polymerization scanning probe microscopy
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Close to original: A DNA‐like double‐stranded polymer is synthesized by ring‐opening metathesis polymerization of a bisnorbornene derivative containing a rigid ferrocene spacer. The polymer forms helices (see picture), supercoils, and ladders, which are observable by scanning tunneling microscopy.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200503406