Constructing 2D porous material based on the assembly of large organic ions: p-sulfonatocalix[8]arene and tetraphenylphosphonium ions

Constructing 2D porous material based on the assembly of large organic ions: p-sulfonatocalix[8]arene and tetraphenylphosphonium ions

In the presence of tetraphenylphosphonium and aquated ytterbium(III) ions, conformationally flexible p-sulfonato-calix[8]arene forms an extended structure with two dimensional porosity involving the assembly of phosphonium cations and 'molecular capsules' comprised of two calixarenes shrou...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-02 (5), p.511-513
Hauptverfasser: Makha, Mohamed, Sobolev, Alexandre N, Raston, Colin L
Format: Artikel
Sprache:eng
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Zusammenfassung:In the presence of tetraphenylphosphonium and aquated ytterbium(III) ions, conformationally flexible p-sulfonato-calix[8]arene forms an extended structure with two dimensional porosity involving the assembly of phosphonium cations and 'molecular capsules' comprised of two calixarenes shrouding three phosphonium cations.
ISSN:1359-7345
1364-548X
DOI:10.1039/b514833b