A simple model for the water o-H2 complex

A simple model for the water o-H2 complex

The infrared spectrum of the complex between o-H2 and H2O, D2O, or HDO, isolated in a matrix of solid p-H2, has been studied between 20 and 4500 cm(-1). In addition the infrared spectrum of the complex between p-D2 and H2O in solid o-D2 has been studied. The spectral shifts are interpreted as the re...

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Veröffentlicht in:The Journal of chemical physics 2006-01, Vol.124 (2), p.024504-024504
Hauptverfasser: Ceponkus, Justinas, Nelander, Bengt
Format: Artikel
Sprache:eng
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Zusammenfassung:The infrared spectrum of the complex between o-H2 and H2O, D2O, or HDO, isolated in a matrix of solid p-H2, has been studied between 20 and 4500 cm(-1). In addition the infrared spectrum of the complex between p-D2 and H2O in solid o-D2 has been studied. The spectral shifts are interpreted as the result of the quadrupole-dipole interaction between hydrogen and water.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.2148410