A Planar Water Tetramer with Tetrahedrally Coordinated Water Embedded in a Hydrogen Bonding Network of [Tc4(CO)12-(μ3-OH)4·4H2O]

A virtually planar water tetramer in which the water molecules are virtually tetrahedrally coordinated could be realized in the solid in a three-dimensional network of [Tc 4(CO)12-(μ 3 −OH)4·4H 2O]. The network could be produced by cocrystallization of the new cubane-like cluster [Tc(CO)3-(μ3-OH)]4...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-01, Vol.128 (2), p.424-425
Hauptverfasser:	Zuhayra, Maaz, Kampen, Willm Uwe, Henze, Eberhard, Soti, Zsolt, Zsolnai, Laslo, Huttner, Gottfried, Oberdorfer, Franz
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl and nitrosyl compounds, and their complexes Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Physics Single-crystal and powder diffraction Structure of solids and liquids crystallography Structure of specific crystalline solids X-ray diffraction and scattering
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Zusammenfassung:	A virtually planar water tetramer in which the water molecules are virtually tetrahedrally coordinated could be realized in the solid in a three-dimensional network of [Tc 4(CO)12-(μ 3 −OH)4·4H 2O]. The network could be produced by cocrystallization of the new cubane-like cluster [Tc(CO)3-(μ3-OH)]4 and water as a complementary component. The amphiphilic behavior of cluster and water results in a highly ordered three-dimensional network. The complementary components, the water tetramer and the cubic cluster, independently of one another form two interpenetrating tetragonal lattice networks held together exclusively by hydrogen bonds.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja057142j