Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers

Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers

In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one‐dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross‐linking (see picture). The main factors that influence this polymerization are the channel size and hos...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (26), p.4987-4990
Hauptverfasser: Uemura, Takashi, Hiramatsu, Daisuke, Kubota, Yoshiki, Takata, Masaki, Kitagawa, Susumu
Format: Artikel
Sprache:eng
Schlagworte:
coordination polymers
inclusion compounds
polymerization
radical reactions
topochemistry
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Zusammenfassung:In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one‐dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross‐linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200700242