3,3-Diphenyl-6-(p-toluenesulfonyl)-6-aza-3-silabicyclo[3.1.0]hexane

The title compound, C23H23NO2SSi, at 100 K adopts a boat conformation which brings the C-H bond of an axial phenyl substituent into proximity [C...N = 3.376 (1) A] with the aziridine lone pair. The factors which favour this conformation for bicyclo[3.1.0]hexane systems are considered.

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Bibliographische Detailangaben
Veröffentlicht in:	Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2001-01, Vol.57 (Pt 1), p.120-122
Hauptverfasser:	MATTHEWS, Jennifer L, MCARTHUR, Duncan R, MUIR, Kenneth W, WHITE, David N. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic compounds Organometalloidal and organometallic compounds Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	The title compound, C23H23NO2SSi, at 100 K adopts a boat conformation which brings the C-H bond of an axial phenyl substituent into proximity [C...N = 3.376 (1) A] with the aziridine lone pair. The factors which favour this conformation for bicyclo[3.1.0]hexane systems are considered.
ISSN:	0108-2701 1600-5759
DOI:	10.1107/S0108270100015638