Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte

We report the design and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates, and electrolyte flow rate on fuel cell performance to obtain...

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Veröffentlicht in:Langmuir 2007-06, Vol.23 (13), p.6871-6874
Hauptverfasser: Jayashree, Ranga S, Mitchell, Michael, Natarajan, Dilip, Markoski, Larry J, Kenis, Paul J. A
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Sprache:eng
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Zusammenfassung:We report the design and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates, and electrolyte flow rate on fuel cell performance to obtain a maximum power density of 191 mW/cm2. This flowing electrolyte design avoids water management issues, including cathode flooding and anode dry out. Placing a reference electrode in the outlet stream allows for independent analysis of the polarization losses on the anode and the cathode, thereby creating an elegant catalyst characterization and optimization tool.
ISSN:0743-7463
1520-5827
DOI:10.1021/la063673p