X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 degrees C

X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 degrees C

The title compound, prepared from C(60) and CF(3)I at 500 degrees C, exhibits an unusual fullerene(X)12 addition pattern that is 40 kJ mol(-1) less stable than the previously reported C(60)(CF(3))12 isomer.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-04 (16), p.1650-1652
Hauptverfasser: Kareev, Ivan E, Shustova, Natalia B, Peryshkov, Dmitry V, Lebedkin, Sergey F, Miller, Susie M, Anderson, Oren P, Popov, Alexey A, Boltalina, Olga V, Strauss, Steven H
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Sprache:eng
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Zusammenfassung:The title compound, prepared from C(60) and CF(3)I at 500 degrees C, exhibits an unusual fullerene(X)12 addition pattern that is 40 kJ mol(-1) less stable than the previously reported C(60)(CF(3))12 isomer.
ISSN:1359-7345