Synthesis of Glycosyl Boranophosphates and Their Applications as Precursors of Glycosyl Phosphate Analogues

Synthesis of Glycosyl Boranophosphates and Their Applications as Precursors of Glycosyl Phosphate Analogues

Glycosyl boranophosphate triesters were synthesized via a boranophosphorylation of reducing sugars. The usefulness of the resultant glycosyl boranophosphates as versatile chemically stable precursors of various glycosyl phosphate derivatives is demonstrated.

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Veröffentlicht in:Organic letters 2008-04, Vol.10 (8), p.1557-1560
Hauptverfasser: Matsumura, Fumiko, Oka, Natsuhisa, Wada, Takeshi
Format: Artikel
Sprache:eng
Schlagworte:
Boron Compounds - chemical synthesis
Glucose - chemistry
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Zusammenfassung:Glycosyl boranophosphate triesters were synthesized via a boranophosphorylation of reducing sugars. The usefulness of the resultant glycosyl boranophosphates as versatile chemically stable precursors of various glycosyl phosphate derivatives is demonstrated.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol800205e