Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines via palladium-catalysed hydride-transfer reaction
Mono- and 1,3-disubstituted allenes were synthesized from the corresponding propargylamines via palladium-catalysed hydride-transfer reaction. In the current transformation, propargylic amines can be handled as allenyl anion equivalents and introduced into various electrophiles to be transformed int...
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Veröffentlicht in: | Organic & biomolecular chemistry 2008-01, Vol.6 (8), p.1471-1477 |
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container_title | Organic & biomolecular chemistry |
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creator | Nakamura, Hiroyuki Ishikura, Makoto Sugiishi, Tsuyuka Kamakura, Takaya Biellmann, Jean-François |
description | Mono- and 1,3-disubstituted allenes were synthesized from the corresponding propargylamines via palladium-catalysed hydride-transfer reaction. In the current transformation, propargylic amines can be handled as allenyl anion equivalents and introduced into various electrophiles to be transformed into allenes under palladium-catalyzed conditions. |
doi_str_mv | 10.1039/b718298h |
format | Article |
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In the current transformation, propargylic amines can be handled as allenyl anion equivalents and introduced into various electrophiles to be transformed into allenes under palladium-catalyzed conditions.</abstract><cop>England</cop><pmid>18385854</pmid><doi>10.1039/b718298h</doi><tpages>7</tpages></addata></record> |
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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Alkadienes - chemical synthesis Alkadienes - chemistry Alkynes - chemistry Amines - chemistry Catalysis Hydrogen - chemistry Ligands Molecular Structure Palladium - chemistry Stereoisomerism |
title | Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines via palladium-catalysed hydride-transfer reaction |
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