Non-classical NHC transfers from the reaction of (IMes)AgCl with osmium carbonyl clusters

Non-classical NHC transfers from the reaction of (IMes)AgCl with osmium carbonyl clusters

N-Heterocyclic carbene transfer reactions were attempted using IMesAgCl and two osmium clusters. The products isolated from these reactions suggest that NHC transfers can be unpredictable.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2007-01 (18), p.1755-1758
Hauptverfasser: Cooke, Craig E, Ramnial, Taramatee, Jennings, Michael C, Pomeroy, Roland K, Clyburne, Jason A C
Format: Artikel
Sprache:eng
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Zusammenfassung:N-Heterocyclic carbene transfer reactions were attempted using IMesAgCl and two osmium clusters. The products isolated from these reactions suggest that NHC transfers can be unpredictable.
ISSN:1477-9226
1477-9234
DOI:10.1039/b703071c