Coordination Copolymerization of Polar Vinyl Monomers H₂C==CHX

Coordination Copolymerization of Polar Vinyl Monomers H₂C==CHX

Rising to the challenge: Neutral phosphinosulfonate PdII complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H2CCHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA=m...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (14), p.2538-2542
Hauptverfasser: Berkefeld, Andreas, Mecking, Stefan
Format: Artikel
Sprache:eng
Schlagworte:
copolymerization
homogeneous catalysis
palladium
polymers
polyolefins
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Zusammenfassung:Rising to the challenge: Neutral phosphinosulfonate PdII complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H2CCHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA=methyl acrylate).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200704642