Cyclophosphazene-Supported Tetranuclear Copper Assembly Containing 15 Contiguous Inorganic Rings

Cyclophosphazene-Supported Tetranuclear Copper Assembly Containing 15 Contiguous Inorganic Rings

The cyclophosphazene hydrazide gem-N3P3Ph2[N(Me)NH2]4 was reacted with o-hydroxybenzaldehyde to afford the multisite coordination ligand gem-N3P3Ph2[N(Me)NCHC6H4-2-OH]4 (LH4). The latter reacted with copper(II) salts to afford a novel tetranuclear copper assembly {N3P3Ph2[N(Me)NCHC6H4-2-O]4Cu2}2,...

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Veröffentlicht in:Inorganic chemistry 2008-03, Vol.47 (6), p.1922-1924
Hauptverfasser: Chandrasekhar, Vadapalli, Andavan, Gurusamy Thangavelu Senthil, Azhakar, Ramachandran, Pandian, Balasubramanian Murugesa
Format: Artikel
Sprache:eng
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Zusammenfassung:The cyclophosphazene hydrazide gem-N3P3Ph2[N(Me)NH2]4 was reacted with o-hydroxybenzaldehyde to afford the multisite coordination ligand gem-N3P3Ph2[N(Me)NCHC6H4-2-OH]4 (LH4). The latter reacted with copper(II) salts to afford a novel tetranuclear copper assembly {N3P3Ph2[N(Me)NCHC6H4-2-O]4Cu2}2, which contains, remarkably, 15 contiguous inorganic rings.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic702500n