Hydrophobic Encapsulation of Hydrocarbon Gases

Encapsulation data for hydrophobic hydrocarbon gases within a water-soluble hemicarcerand in aqueous solution are reported. It is concluded that hydrophobic interactions serve as the primary driving force for the encapsulation, which can be used for the design of gas-separating polymers with intrins...

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Veröffentlicht in:	Organic letters 2007-04, Vol.9 (9), p.1753-1755
Hauptverfasser:	Leontiev, Alexander V, Saleh, Anas W, Rudkevich, Dmitry M
Format:	Artikel
Sprache:	eng
Schlagworte:	Gases Hydrocarbons - chemistry Hydrophobic and Hydrophilic Interactions Magnetic Resonance Spectroscopy Models, Molecular Molecular Structure
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Encapsulation data for hydrophobic hydrocarbon gases within a water-soluble hemicarcerand in aqueous solution are reported. It is concluded that hydrophobic interactions serve as the primary driving force for the encapsulation, which can be used for the design of gas-separating polymers with intrinsic inner cavities.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol070465v