Redox-Switching of Nonlinear Optical Behavior in Langmuir−Blodgett Thin Films Containing a Ruthenium(II) Ammine Complex

Redox-Switching of Nonlinear Optical Behavior in Langmuir−Blodgett Thin Films Containing a Ruthenium(II) Ammine Complex

Alternating Langmuir−Blodgett multilayers containing a metal-to-ligand charge-transfer chromophore based on {RuII(NH3)5}2+ show redox-switching of the second harmonic generation from a 1064 nm laser.

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Veröffentlicht in:Journal of the American Chemical Society 2008-03, Vol.130 (11), p.3286-3287
Hauptverfasser: Boubekeur-Lecaque, Leïla, Coe, Benjamin J, Clays, Koen, Foerier, Stijn, Verbiest, Thierry, Asselberghs, Inge
Format: Artikel
Sprache:eng
Schlagworte:
Amines - chemistry
Electrochemistry
Membranes, Artificial
Molecular Structure
Optics and Photonics
Organometallic Compounds - chemistry
Oxidation-Reduction
Ruthenium - chemistry
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Zusammenfassung:Alternating Langmuir−Blodgett multilayers containing a metal-to-ligand charge-transfer chromophore based on {RuII(NH3)5}2+ show redox-switching of the second harmonic generation from a 1064 nm laser.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja711170q