Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Methanol-Stable Platforms Analogous to the Adenine-Thymine Base Pair
Complementary partners: A combinatorial library of self‐assembled ligand systems has been designed by analogy to the A–T base pair. When these ligand systems are applied in the rhodium‐catalyzed hydroformylation of 1‐octene (see scheme), high regioselectivities (rs) are obtained, even in the protic...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2007-01, Vol.46 (17), p.3037-3039 |
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| container_issue | 17 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Waloch, Christoph Wieland, Jörg Keller, Manfred Breit, Bernhard |
| description | Complementary partners: A combinatorial library of self‐assembled ligand systems has been designed by analogy to the A–T base pair. When these ligand systems are applied in the rhodium‐catalyzed hydroformylation of 1‐octene (see scheme), high regioselectivities (rs) are obtained, even in the protic solvent methanol. |
| doi_str_mv | 10.1002/anie.200605202 |
| format | Article |
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| ispartof | Angewandte Chemie International Edition, 2007-01, Vol.46 (17), p.3037-3039 |
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| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Adenine - analogs & derivatives Adenine - chemistry Base Pairing Catalysis combinatorial chemistry homogeneous catalysis hydroformylation Ligands Magnetic Resonance Spectroscopy Methanol - chemistry Molecular Structure rhodium self-assembly Thymine - analogs & derivatives Thymine - chemistry |
| title | Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Methanol-Stable Platforms Analogous to the Adenine-Thymine Base Pair |
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