Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Methanol-Stable Platforms Analogous to the Adenine-Thymine Base Pair

Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Methanol-Stable Platforms Analogous to the Adenine-Thymine Base Pair

Complementary partners: A combinatorial library of self‐assembled ligand systems has been designed by analogy to the A–T base pair. When these ligand systems are applied in the rhodium‐catalyzed hydroformylation of 1‐octene (see scheme), high regioselectivities (rs) are obtained, even in the protic...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (17), p.3037-3039
Hauptverfasser: Waloch, Christoph, Wieland, Jörg, Keller, Manfred, Breit, Bernhard
Format: Artikel
Sprache:eng
Schlagworte:
Adenine - analogs & derivatives
Adenine - chemistry
Base Pairing
Catalysis
combinatorial chemistry
homogeneous catalysis
hydroformylation
Ligands
Magnetic Resonance Spectroscopy
Methanol - chemistry
Molecular Structure
rhodium
self-assembly
Thymine - analogs & derivatives
Thymine - chemistry
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Beschreibung
Zusammenfassung:Complementary partners: A combinatorial library of self‐assembled ligand systems has been designed by analogy to the A–T base pair. When these ligand systems are applied in the rhodium‐catalyzed hydroformylation of 1‐octene (see scheme), high regioselectivities (rs) are obtained, even in the protic solvent methanol.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200605202