Arene-Sandwiched Silver(I) Pyrazolates

Arene-Sandwiched Silver(I) Pyrazolates

A silver filling: The π‐acidic, trinuclear silver(I) pyrazolate [{[3,5‐(CF3)2pz]Ag}3] readily reacts with simple electron‐rich aromatic hydrocarbon compounds to form sandwich complexes. The type of complex formed depends on the solvent and the arene, and includes supramolecular stacks. Additionally,...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (13), p.2192-2194
Hauptverfasser: Rasika Dias, H. V., Palehepitiya Gamage, Chammi S.
Format: Artikel
Sprache:eng
Schlagworte:
host-guest systems
Lewis acids
N ligands
sandwich complexes
silver
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Beschreibung
Zusammenfassung:A silver filling: The π‐acidic, trinuclear silver(I) pyrazolate [{[3,5‐(CF3)2pz]Ag}3] readily reacts with simple electron‐rich aromatic hydrocarbon compounds to form sandwich complexes. The type of complex formed depends on the solvent and the arene, and includes supramolecular stacks. Additionally, some of these complexes appear to have interesting luminescence properties.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604585