Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters

The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chir...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2007-01, Vol.9 (14), p.1676-1679
Hauptverfasser:	FILIPPI, Antonello, GIARDINI, Anna, MARCANTONI, Enrico, PALADINI, Alessandra, PICCIRILLO, Susanna, RENZI, Gabriele, RONDINO, Flaminia, ROSELLI, Graziella, SATTA, Mauro, SPERANZA, Maurizio
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene Derivatives - chemistry Chemistry Electrons Exact sciences and technology General and physical chemistry Lasers Mass Spectrometry - instrumentation Mass Spectrometry - methods Models, Chemical Noble Gases - chemistry Spectrum Analysis - instrumentation Spectrum Analysis - methods Stereoisomerism
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Zusammenfassung:	The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.
ISSN:	1463-9076 1463-9084
DOI:	10.1039/b702257n