Observation of Cu2+-H2 Interactions in a Fully Desolvated Sodalite-Type Metal-Organic Framework
Metal–H2 binding: A new tetrazolate‐based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N bl...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2007-02, Vol.46 (9), p.1419-1422 |
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| container_end_page | 1422 |
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| container_issue | 9 |
| container_start_page | 1419 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 46 |
| creator | Dincă, Mircea Han, Won Seok Liu, Yun Dailly, Anne Brown, Craig M. Long, Jeffrey R. |
| description | Metal–H2 binding: A new tetrazolate‐based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green). |
| doi_str_mv | 10.1002/anie.200604362 |
| format | Article |
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| language | eng |
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| subjects | copper hydrogen metal-organic frameworks microporous materials neutron diffraction |
| title | Observation of Cu2+-H2 Interactions in a Fully Desolvated Sodalite-Type Metal-Organic Framework |
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