Observation of Cu2+-H2 Interactions in a Fully Desolvated Sodalite-Type Metal-Organic Framework

Observation of Cu2+-H2 Interactions in a Fully Desolvated Sodalite-Type Metal-Organic Framework

Metal–H2 binding: A new tetrazolate‐based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N bl...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-02, Vol.46 (9), p.1419-1422
Hauptverfasser: Dincă, Mircea, Han, Won Seok, Liu, Yun, Dailly, Anne, Brown, Craig M., Long, Jeffrey R.
Format: Artikel
Sprache:eng
Schlagworte:
copper
hydrogen
metal-organic frameworks
microporous materials
neutron diffraction
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Zusammenfassung:Metal–H2 binding: A new tetrazolate‐based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604362