Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes
Gold(I)-catalysed addition of electron-rich arenes and heteroarenes to 1,6-enynes gives two different types of products by reaction of the intermediate cyclopropyl gold carbenes at the cyclopropane or at the carbene.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2007-01 (7), p.698-700 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Gold(I)-catalysed addition of electron-rich arenes and heteroarenes to 1,6-enynes gives two different types of products by reaction of the intermediate cyclopropyl gold carbenes at the cyclopropane or at the carbene. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b615335f |