Orientational and translational dynamics in room temperature ionic liquids

The authors investigate the dynamics of a series of room temperature ionic liquids, based on the same 1-butyl-3-methylimidazolium cation with different anions, by means of broadband ( 10 − 6 - 10 9 Hz ) dielectric spectroscopy and depolarized light scattering in the temperature range from 400 K down to 35 K . Typical ionic conductivity is observed above the glass transition temperature T g . Below T g the authors detect relaxation processes that exhibit characteristics of secondary relaxations, as typically observed in molecular glasses. At high temperatures, the characteristic times of cation reorientation, deduced from the light scattering data, are approximately equal to the electric modulus relaxation times related to ionic conductivity. In the supercooled regime and close to T g , the authors observe decoupling of conductivity from structural relaxation. Overall, room temperature ionic liquids exhibit typical glass transition dynamics, apparently unaltered by Coulomb interactions.