Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes
A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S−H bonds across electron-deficient olefins to regioselectively produ...
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| Veröffentlicht in: | Inorganic chemistry 2007-04, Vol.46 (7), p.2365-2367 |
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| container_end_page | 2367 |
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| container_issue | 7 |
| container_start_page | 2365 |
| container_title | Inorganic chemistry |
| container_volume | 46 |
| creator | Delp, Samuel A Munro-Leighton, Colleen Goj, Laurel A Ramírez, Magaly A Gunnoe, T. Brent Petersen, Jeffrey L Boyle, Paul D |
| description | A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S−H bonds across electron-deficient olefins to regioselectively produce “anti-Markovnikov” products. |
| doi_str_mv | 10.1021/ic070268s |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0020-1669 |
| ispartof | Inorganic chemistry, 2007-04, Vol.46 (7), p.2365-2367 |
| issn | 0020-1669 1520-510X |
| language | eng |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Alkenes - chemistry Catalysis Copper - chemistry Electrons Hydrogen - chemistry Ligands Models, Molecular Molecular Conformation Sulfhydryl Compounds - chemistry Sulfur - chemistry |
| title | Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes |
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