Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes

Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes

A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S−H bonds across electron-deficient olefins to regioselectively produ...

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Veröffentlicht in:Inorganic chemistry 2007-04, Vol.46 (7), p.2365-2367
Hauptverfasser: Delp, Samuel A, Munro-Leighton, Colleen, Goj, Laurel A, Ramírez, Magaly A, Gunnoe, T. Brent, Petersen, Jeffrey L, Boyle, Paul D
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Catalysis
Copper - chemistry
Electrons
Hydrogen - chemistry
Ligands
Models, Molecular
Molecular Conformation
Sulfhydryl Compounds - chemistry
Sulfur - chemistry
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Beschreibung
Zusammenfassung:A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S−H bonds across electron-deficient olefins to regioselectively produce “anti-Markovnikov” products.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic070268s