[{2,6-(Me₂NCH₂)₂C₆H₃}Sn]₂: An Intramolecularly Coordinated Diorganodistannyne

Not only steric protection by bulky substituents but also intramolecular N→Sn coordination makes possible the isolation and characterization of dimeric organotin(I) compounds such as [{2,6‐(Me2NCH2)2C6H3}Sn]2 (see structure), which according to a crystallographic study exhibits a SnSn bond length o...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-02, Vol.47 (9), p.1650-1653
Hauptverfasser:	Jambor, Roman, Kašná, Blanka, Kirschner, Karl N, Schürmann, Markus, Jurkschat, Klaus
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallization Group 14 elements intramolecular coordination main-group elements Molecular Structure NMR spectroscopy organotin compounds Organotin Compounds - chemical synthesis Organotin Compounds - chemistry X-Ray Diffraction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Not only steric protection by bulky substituents but also intramolecular N→Sn coordination makes possible the isolation and characterization of dimeric organotin(I) compounds such as [{2,6‐(Me2NCH2)2C6H3}Sn]2 (see structure), which according to a crystallographic study exhibits a SnSn bond length of 2.9712(12) Å.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200704635